Sunday, September 1, 2019

Ash From Palm Oil Waste Combustion As A Biomaterial In Concrete Construction

Palm kernel shells (PKS) and mesocarp fibres are commonly used as fuel for palm oil mills for the production of electricity and steam for sterilizers. The byproduct of combustion in the form of ash a lot produced by the process. A palm oil mill can produce 5 tons / day or more of the ash depending on the amount burned because the average ash content of the palm oil waste is around 5%. Most of the palm oil mills do not make use of the residual ash from the combustion but just throw it away. Though the ash can actually be used for various purposes, one of which is as a biomaterial substitute for sand in various building construction projects. The locations of palm oil mills or surrounding communities usually in the remote areas difficult to obtain a supply of sand for the construction of various buildings, so that the presence of ash as a substitute for sand will be helped.
Typical boiler in palm oil mill
At present, a number of domestic industries have started to use biomass fuel, as an environmentally friendly fuel. Palm kernel shell or PKS is one of the favorite biomass fuels at this time. One of the interesting things about palm kernel shells is that they are  almost similar properties to wood pellets, but at a lower price. Ash from the palm kernel shells as well as ash from the palm oil mills can also be used for sand substitution for various building construction projects. The location of industries in urban areas so that the use of ash can also be in line with various city construction constructions such as the construction of roads, high rise buildings and aircraft runways. Although the ash cannot replace 100% sand but it will help save costs by around 25% substituted with the ash.
Main chemical compounds content in sand
Main chemical compounds content in boiler bottom ash
The palm kernel shell ash itself contains high silica which is around 60%, while the ash mixture from the shell and palm fiber in the boiler furnace contains about 30% SiO2. SiO2 functions as a filler in the manufacture of concrete which will affect the strength of the concrete. While the composition of the main compounds in the sand can be seen that SiO2 has a relatively large composition. Mud in sand is impurity so that the mud content in sand cannot exceed 5%. Mud levels of more than 5% result in the hydrogen bonding of cement paste and sand being reduced due to the influence of sludge as impurities. Boilers ash from palm oil mills can be used as a substitute for sand in making concrete because it has compounds that play a role in making concrete. If it is to be used as a cement substitution material, a material must contain a relatively large amount of lime compounds because cement basically functions as a binder and mainly functions as lime. The content of SiO2, Al2O3, and CaO is contained in boiler scale ash (bottom ash) which is needed in making concrete.

The yield of ash density is 2.11 g / cm3, lower than the density of sand. According to ASTM C128-93, the good density for making concrete is above 2.50% so it includes rough aggregate. The absorption value of water produced by boiler scale ash fulfills the requirements of preventing or reducing empty voids in concrete. The maximum limit of SiO2 content contained in sand for making concrete is around 30%, so that the boiler bottom ash is included in a good aggregate and meets the standard for partial sand replacement. Based on the composition of the chemical content, boiler bottom ash is superior to sand because CaO in ash plays a role in helping cement as a binding material. Similarly Al2O3 is very influential in accelerating hardening of concrete.
Comprehensive concrete strength tester
If calculated the potential ash from the waste of palm oil is also quite large potential. Say with 1,000 palm oil mills now operating in Indonesia with each mill producing 5 tons / day of ash then 5,000 tons of ash a day or 150,000 tons of ash a month. While the excess of palm kernel shells from palm oil mills that can be utilized by other industries in Indonesia is estimated to reach 11 million tons, which means that the ash potential that can be produced is 550 thousand tons. In addition, the difference between ash from palm oil waste classified as biomass ash and coal ash is palm kernel shell ash excluding B3 (hazardous) waste so handling is easier while coal ash including B3 (hazardous)waste whose handling is more difficult. Palm kernel shell ash also comes from biomass which is a renewable resource while coal is from non-renewable resource group.

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