Energy Plantations Energy Sources for All Time

 "Allah who makes fire for you from green wood, then you kindle (fire) from it." (QS. Yaasin (36): 80)

The sun was created by Allah SWT as the main source of energy for humans and living things on earth. It takes about 8 minutes for sunlight to reach the earth and is converted by plants into a food source so that it can be consumed by animals and humans. Humans also get food from animal sources. The more sunlight, the more can be converted by plants through the process of photosynthesis. Without the sun, plants die, animals die, humans die so that there will be no life on earth. Fossil fuels are essentially a source of energy from plants and animals in the past. Mining and use of fossil fuels will release a number of greenhouse gases (GHG) which increase the earth's temperature which at a certain level is dangerous for the earth's population itself. Efforts to overcome this are by using non-fossil energy and renewable energy so as not to contribute to increasing the concentration of GHG in the atmosphere which increases the earth's temperature.

From plants or trees can be directly used as a source of energy or fuel, namely firewood. Derivatives or energy products from plants are also very diverse and can meet all human needs, both energy in the form of solid fuels, liquid fuels and gas fuels. The production of firewood, wood chips, wood briquettes, sawdust, torrified biomass to charcoal are a number of solid fuel products. While the production of biooil, bioethanol, biodiesel, renewable diesel / green diesel, and bioavtur / bio jet fuel are a number of liquid fuels. And biogas and bio-syngas are gas fuels that can be produced from the original material in the form of plants.

A number of conversion techniques based on physics, chemistry and biology are needed for the conversion. The use of appropriate plant species is also needed to facilitate the conversion, for example for the production of solid fuels, biomass sources such as wood are needed, while if the target is liquid fuel, then the type of oil-producing plants that need to be pursued. Conversion from solid fuels to liquid or gas fuels can also be done but in general the longer and more complicated the process, the more expensive the production costs will be. But still, energy plantations are the basis for all of that.

Popular and fairly easy biomass processing is to make wood chips with size reduction then wood pellets and wood briquettes through biomass densification. Furthermore, to convert sugary biomass into ethanol with fermentation and azeotropic distillation, convert lignin biomass (lignocellulosic biomass) into ethanol with enzymatic hydrolysis reactions followed by fermentation and azeotropic distillation. Converting woody biomass into fuel with a thermal process can be burned directly or if you want to make charcoal, concentrate the fixed carbon, namely by pyrolysis or carbonization, and if you want to maximize liquid products / bio-oil / pyro-oil, namely by fast pyrolysis and if you want to maximize gas products, namely by gasification. And so that the characteristics of the biomass are like hydrophobic coal, the torrefaction or mild-pyrolysis process can be carried out. Torrefaction and densification are usually carried out together to optimize the biomass fuel product.

With gas to liquid (GTL) namely the gasification process and followed by the Fisher - Tropsch process, bio-ethanol, biodiesel and bioavtur / bio jet fuel can be produced. While from groups of plants that produce oil such as palm oil, biodiesel can be made especially with the transesterification or estran (esterification plus transesterification) process. Even used oil or used cooking oil / used cooking oil and miko (minyak kotor) / dirty oil or PAO (palm acid oil) can also be used for biodiesel / green diesel or further processed into bio-jet fuel / bio-avtur with the HVO / HEFA - SPK (Hydro-processed Esters and Fatty Acids-Synthesized Paraffinic Kerosene) process.

So basically, biomass from trees can be processed into various forms of energy or fuel needed by humans. In addition to being used directly as a heat source, this energy can also be converted into mechanical energy or electrical energy, for example biofuel-fueled vehicles to biomass power plants. So the source of energy throughout the ages stored in plants is this biomass as stated by Allah SWT in the verse above and there is no doubt whatsoever about it. Indonesia as a tropical country is a "heaven" for the production of biomass because of the rays of sunlight throughout the year and adequate rainfall and extensive land. The storage of energy in plants from sunlight is also likened to a battery that can be used anytime and anywhere for more details read here.

Another important thing to note for the creation of energy plantations or biomass plantations is the status of the land used. The land must not be from deforestation or land conversion (land use change) that damages the environment. Industrial plantation forests (HTI) that are in accordance with their designation can be used as energy plantations. In addition, biomass for producing energy can also be cultivated on critical land, or referred to as 'unproductive' land. The Indonesia Ministry of Environment and Forestry (KLHK) estimates that critical land in Indonesia in 2016 was 24.3 million hectares (Times Indonesia, 2017). This is a very large area, and overall Indonesia's territory is large enough to provide biomass for renewable energy production.

PAO and UCO Become Bio-Jet Fuel

Decarbonization has entered all lines including the air transportation sector. Aviation fuel must also gradually shift from fossil fuels to sustainable renewable fuels. However, decarbonization in this sector is still slow, namely currently only around 0.01% of the use of sustainable renewable fuels or SAF (Sustainable Aviation Fuel) globally for these aircraft. These barriers include technological maturity or technological readiness, certification for SAF conversion or production process routes, scale up and commercialization, price gaps with fossil fuels, and competition with biofuels in the land transportation sector. The Carbon Offsetting and Reduction Scheme for International Aviation (CORSIA) has initiated a reduction in GHG emissions for global aviation. Using the 2019 baseline, it is estimated that around 2.5 billion tonnes of CO2 emissions need to be offset / reduced in the 2021-2035 period to achieve carbon neutral growth. CORSIA also plans its implementation in three phases, namely the pilot phase in 2021-2023, the first phase in 2024-2026 and the second phase in 2027-2035. Participation of member countries is voluntary in the first two phases (2021-2026) and mandatory in the 2027 phase and beyond, except for the least developed countries, small developing countries and landlocked countries.

Until now, HVO / HEFA - SPK (Hydro-processed Esters and Fatty Acids-Synthesized paraffinic kerosene) technology using vegetable oil including waste oil is the only technology that is most ready for the conversion or production of SAF. Currently, the technology readiness level (TRL) and feedstock readiness level (FRL) are at level 9, meaning that it is the most ready among other conversion technology routes. One of the advantages of HVO technology is the flexibility of using various feedstocks / raw materials so that waste oil such as PAO or mico from palm oil mill ponds and also used cooking oil or used cooking oil or UCO are also very potential to be converted into SAF with HVO technology. But in fact, even though HVO technology can directly produce SAF, most of the HVO technology is used for the production of diesel engine fuel for land transportation or commonly called green diesel or renewable diesel. Green diesel or renewable diesel is different from biodiesel or FAME-based biodiesel which is produced by the transesterification process. And green diesel or renewable diesel from HVO also has a number of advantages compared to FAME based biodiesel.

HVO production is also not a new technology. Globally, there are a number of large-capacity commercial HVO plants that use vegetable oil as raw material. The largest plants are Neste in Rotterdam and Singapore with a capacity of 1.28 billion liters per year and Diamond Green Diesel in Louisiana with a capacity of 1.04 billion liters per year. HVO production is closer to petroleum refining technology than conventional diesel production. This is why oil and gas companies may be more interested in developing it than palm oil companies or conventional biodiesel companies. Palm oil mills have raw materials / feedstock, while oil and gas companies may be more relevant to downstream development because of the readiness to adapt technology and develop end products.

HVO is produced by hydrogenation and hydrocracking of vegetable oils and animal fats using hydrogen and catalysts at high temperature and pressure. In this hydrotreating process, oxygen is released from the feedstock consisting of triglycerides and / or fatty acids. This will produce straight chain hydrocarbons (paraffins) with various properties and molecular sizes depending on the characteristics of the raw materials and the operating conditions of the process being carried out. This conversion usually goes through two stages, namely hydrotreatment followed by hydrocracking / isomerization. This hydrotreatment process is usually carried out at a temperature of 300 -390 C and for triglyceride treatment, propane is usually produced as a by-product. The final product of straight chain hydrocarbons can be adjusted according to certain fuel types such as bio jet fuel or SAF. Currently HVO is the third most common biofuel in the world after ethanol and FAME based biodiesel.

PAO is produced as waste or by-product of palm oil mills. PAO will always be produced because palm oil mills cannot have an efficiency level of 100% and the less efficient the palm oil mill, the more oil becomes waste or by-product in the form of PAO. It is estimated that there are currently 1 million tons of PAO in Indonesia and 0.5 million liters in Malaysia or a total of 1.5 million tons. As for UCO or used cooking oil with the use of cooking oil reaching 1.55 million tons/year assuming 10% can be recovered as used cooking oil or UCO, 155 thousand tons/year are produced. In addition to being part of the effort to overcome waste both in palm oil mills and households that pollute the environment, the production of SAF or bio-jet fuel has also contributed to the decarbonization of the air transportation sector. With HVO / HEFA technology that is able to process waste oil such as PAO and UCO, the more PAO and UCO that can be processed, the better.

SBE Pyrolysis: A Profitable Waste Management Solution

Spent Bleaching Earth (SBE) which is solid waste produced from the bleaching process in the CPO processing industry into cooking oil and oleochemicals is increasing along with the production of palm oil derivative products or downstream palm oil industries such as cooking oil and oleochemicals. The amount of bleaching earth used generally ranges from 0.5-2.0% of the total CPO refined, depending on the quality of the CPO to be processed in the refining process. SBE is included in category 2 hazardous toxic material (B3) waste from specific sources with waste code B413. SBE is categorized as hazardous toxic material (B3) waste because it contains high oil and has characteristics that are flammable and corrosive. SBE can be categorized as non-B3 waste if its oil content is below 3%.

The classification of SBE status as hazardous toxic material (B3) waste in Indonesia is different from the status of SBE in Malaysia, which is also the second largest palm oil producer in the world. SBE waste produced by the Malaysian refinery industry is not classified as B3 waste but is still categorized as solid waste from refinery factories whose processing is regulated in the Solid Waste Regulation (SWR) so that the waste can be reused into products with high economic value.

According to the Indonesian Vegetable Oil Industry Association (GIMNI, 2021), with a refinery capacity of palm oil/CPO between 600 tons to 2,500 tons per day, and assuming the use of bleaching earth (BE) of 1%-2%, the average will produce 6-50 tons of SBE per day. And according to the Directorate General of Waste Management, Toxic and Hazardous Materials (PSLB3) of the Ministry of Environment and Forestry, the SBE produced from the vegetable oil refining process in Indonesia in 2019 reached 779 thousand tons. Of that amount, 51.47% (401 thousand tons) of SBE was processed, while the remaining 48.39% (378 thousand tons) was stored or stockpiled. A very large amount and has the potential to pollute the environment.

SBE has an oil content of around 20-40%, so it has the potential to be utilized. In addition, SBE also contains color, gum, metals namely Silica, Aluminum oxide, Ferrioxide, Magnesia, other metals and water. Basically, SBE processing is done by separating oil from its solids. The separated oil can then be used as raw material for biodiesel and even aircraft fuel (bio-jet fuel) such as POME / PAO and UCO. With the amount of unprocessed SBE reaching around 378 thousand tons per year, the potential oil that can be extracted reaches around 115 thousand tons per year.

With pyrolysis, the process of separating solid and liquid fractions from SBE is easy to do, as well as oil recovery can be maximized, as well as SBE becomes non-hazardous toxic material (non-B3) waste because its oil content is below 3%. More specifically, with continuous pyrolysis, the volume of SBE waste reaching 50 tons per day in the CPO refinery unit can be easily done. The large potential economic value that can be obtained from the utilization of SBE is a shame if it is not optimized. The market opportunity for processed products from SBE waste is also expected to be bright in the future, along with the development of market preferences that demand the availability of eco-friendly and sustainable products.