Activated carbon or activated charcoal
is a material that is widely used in various industries, as auxiliary
processing. Food, beverage, energy, mining and pharmaceutical industries use
this activated carbon. The need for activated carbon also continues to increase
so that production also needs to be expanded. Indonesia has great potential as
a world class activated carbon producer considering the abundance of potential
raw materials available.
Currently, large activated carbon
producers are located outside Indonesia such as Europe and America. Yet neither
Europe nor America have abundant source of raw materials or most imports
including from Indonesia. The most favorite activated carbon feedstock today is
coconut shell and once again Indonesia is the country with the largest coconut
plantation in the world, which is about 3.7 million hectares. Palm kernel shells
can also be the raw material of further choices. With a palm oil plantation
area of approximately 12 million hectares, palm kernel shells produced more
than 10 million tons / year.
The raw material of activated carbon
is charcoal. The charcoal is then activated to become activated carbon. The
process of making charcoal is by carbonization or pyrolysis. Coconut shell as
an example of raw material of charcoal, then after carbonization the coconut
shell convert into coconut shell charcoal, which then this charcoal become the
raw material of activated charcoal. So basically the process of activated
charcoal production is through 2 stages of the process namely pyrolysis
(carbonization) and activation. The process of producing the charcoal or the
carbonization process (pyrolysis) is the same as the biomass carbonization process
in general, for more detail can be read here. Currently in large capacity the
production of charcoal is carried out continuously with indirect-heating.
Rotating kilns and heated auger pyrolyser are commonly used equipment for
continuous production of charcoal. Continuous integration of charcoal
production and activation process can be read here.
While the activation phase can be done
in two ways namely the activation of physics and chemistry. The choice of
activation depends on the target surface area, pore distribution and economy.
Steam activation is the most widely used physics activation, whereas chemical
activation is very diverse. The more surface area of activated carbon the more
expensive the price is also proportional to the cost of production. Activation
equipment commonly used there are 2 kinds namely, rotating kilns and fluidized
bed. Of these 2 types of rotating kiln equipment is more widely used than the
fluidized bed. The price of rotating kiln equipment is cheaper because the
construction and operation are easier than the fluidized bed system. Fluidized
bed systems are typically used for higher quality activated carbon production
due to better distribution and pore engineering due to fluidization.
Standard and quality of activated
carbon is determined primarily by surface area, pore distribution, size and
hardness. The iodine number parameter is commonly used for the quality of
activated carbon. The higher the iodine number the better the activated carbon
quality. The iodine number is a number indicating how much adsorbent or
activated carbon can adsorb iod. The greater the iodine value, the greater the
adsorption power of the adsorbent or the activated charcoal. Conversely, the
higher water content and ash content contained in the activated carbon will
cause many pores to be covered by the impurities so that the surface area will
be smaller. Where the surface area is closely related to the activated carbon
adsorption capacity.All biomass basically can be used as an activated carbon raw
material because it has a carbon content. Specific application of the activated
charbon that determines the choice of raw material and its activation options.
No comments:
Post a Comment