Cogeneration in Palm Oil Mills with Pyrolysis, Initial Steps in Biochar Production and Implementation

The analogy is like cofiring carried out in coal-fired power plants by mixing biomass fuels with a certain ratio as an effort to decarbonize the energy sector in power plants. While in palm oil mills, cogeneration with pyrolysis is an innovative initial step to enter the carbon negative era with the application of biochar, the main product of pyrolysis. And because all palm oil mills use biomass fuel for their mill operations, they are already based on carbon neutral fuel, unlike coal-fired power plants which are based on carbon positive fuels because they come from fossils.

Unlike cofiring which mixes coal and biomass fuels with a certain ratio and then burns them together in a furnace such as pulverized combustion, cogeneration is done by producing energy separately but the energy output is for the same use or especially the same boiler. This is done because the types of fuels may be different, such as solid fuels with liquid fuels or the technology for producing the energy is different. With this cogeneration, it means that not all energy is produced from one energy source or energy from cogeneration is a secondary energy source to meet total energy needs, and in the case of cogeneration in this palm oil mill, energy from combustion is still the primary energy.

Then why not just do full pyrolysis? It is easier, gradually for palm oil mills to adopt pyrolysis technology and its characteristics. Because (slow) pyrolysis aims to maximize solid / biochar, the by-products in the form of excess energy (syngas and biooil) as a source of boiler fuel, the calorific value is not as much as combustion which is indeed intended to maximize heat. Only about 1/3 of the excess energy contributes (cogeneration) as boiler fuel. In other words, if full pyrolysis is carried out directly, the amount of biomass as raw material for pyrolysis becomes 3 times greater or the pyrolysis unit becomes very large so that all palm oil mill biomass waste is used, and the mill cannot sell its palm kernel shells.

What are the benefits obtained by palm oil mills if they carry out cogeneration with pyrolysis for biochar production? Among the biochar products, it can save fertilizer use in oil palm plantations, overcome the problem of empty oil palm bunches (EFB) so that palm oil mills can achieve zero waste, palm kernel shells (PKS) that have been used for boiler fuel can be sold to increase income, the productivity of fresh fruit bunches (FFB) of palm oil increases, the application of biochar in palm oil plantations is also a climate solution (carbon sequestration / carbon sink) so that it can get carbon credit compensation and with good waste management, even zero waste and the application of biochar in palm oil plantations, palm oil companies will get a good image in terms of the environment and sustainability.
 

Maximizing the Rate of CO2 Absorption from the Atmosphere Based on Biomass

Maximizing the rate of CO2 absorption from the atmosphere is very important considering the rate of addition of CO2 concentration to the atmosphere is not comparable to the rate of CO2 absorption. This is what makes the CO2 concentration continue to increase. To balance this speed, a strategy is needed to increase the rate of CO2 absorption. The use of biomass will be very effective and provide multiple benefits for human life. 

CO2 from the atmosphere needs to be captured through biomass production through the process of photosynthesis in plants. Fast-growing species of plants that have high photosynthesis rates are needed for this. Furthermore, biomass, especially wood from fast-growing species of plants, is used as raw material for biochar. Furthermore, biochar is used to improve soil fertility (soil amendment) in various types of agricultural and forestry plants.

Biochar production with slow pyrolysis will also produce excess heat, syngas and biooil that can be used as energy sources. The benefits of biochar production will be obtained from the sale of biochar, the sale of carbon credits and the use of slow pyrolysis by-products. With conditions like this, efforts to increase the speed of CO2 absorption from the atmosphere should be increased. How fast and how much CO2 volume can be absorbed will depend on the type of fast growing species used, the area of ​​planting and the capacity of biochar production. 

Biochar or Biocoal Production?

Biochar and biocoal production are basically one breath. Biochar production with full pyrolysis while biocoal with half/mild pyrolysis (torrefaction). The purpose of torrefaction/mild pyrolysis is to increase its energy content and make it hydrophobic so it is called biocoal. While the purpose of full pyrolysis is to produce stable biocarbon material so that it does not decompose in the soil for hundreds or even thousands of years and improve soil fertility so as to increase plant productivity (agriculture and forestry). 

Current biochar applications are mainly for agriculture and biochar production will produce excess heat, syngas and biooil as energy sources. While biocoal only focuses on energy. The benefits of biochar production are obtained from the sale of biochar, the sale of carbon credits and the utilization of by-products (full) pyrolysis. While the benefits of biocoal are only from the sale of biocoal itself.

The selection or development of a business will be related to business readiness (market, technology, investment, etc.) and other benefits, namely benefits in the social and environmental sectors. 

Biochar from Wood Waste and Forestry Waste

The era of decarbonization and bioeconomy continues and continues to grow over time. While some people focus on the carbon neutral sector such as the production of biomass fuels such as wood pellets, wood briquettes or wood chips, people who focus on negative carbon seem to be fewer, including the use of CCS (Carbon Capture and Storage) and biochar production. Compared to CCS, biochar production with pyrolysis is easier and cheaper so it is projected to become a future trend. Logically, the negative carbon scenario is actually much better because in addition to reducing the concentration of CO2 in the atmosphere, while the neutral carbon scenario only does not increase CO2 emissions in the atmosphere, but does not reduce or absorb CO2 in the atmosphere. CO2 sequestration or biochar carbon removal (BCR) is currently also the most industrially relevant carbon removal technology. BCR is a key solution for real climate change mitigation today and its development is very rapid. BCR also has a vital role in the carbon removal technology portfolio. 

Woody biomass, especially from wood industrial waste and forestry waste, is a potential raw material for biochar production, even this type of wood biomass is the best raw material because it can produce high quality biochar, namely fixed carbon of more than 80%. The potential for wood biomass raw materials in Indonesia is very large, estimated at 29 million m3/year from forest harvesting waste, and 2 million m3/year from wood processing industry waste including 0.78 million m3 in the form of sawdust (the yield of the sawmill industry ranges from 50-60% and as much as 15-20% consists of sawdust). And that does not include if there is a biomass plantation or energy plantation dedicated to biochar production.

With the condition of agricultural land, plantations and forestry which are experiencing a lot of degradation, the need for biochar is also very large. Among the factors causing the decline in land fertility is the use of chemical fertilizers and pesticides for decades continuously and tends to be excessive. This causes a decline in soil quality which has an impact on crop production because it makes the land more acidic and hard which is estimated to reach millions of hectares. In addition, the price of chemical fertilizers is increasingly expensive and difficult to obtain, which results in low agricultural production, so the government is forced to import several agricultural commodities to meet the needs of the community. This actually does not need to happen considering the potential land in Indonesia is very large, it only needs to improve the condition of the land so that it can be optimal again. Making damaged land fertile is not difficult, it only takes perseverance to repair and care for the land so that it continues to be fertile.

Meanwhile, dry land consists of ultisol soil of 47.5 million ha and oxisol of 18 million ha. Indonesia has a coastline of 106,000 km with a potential land area of ​​1,060,000 ha, generally including marginal land. Millions of hectares of marginal land are spread across several islands, have good prospects for agricultural development but are currently not well managed. The land has a low fertility rate, so technological innovation is needed to improve and increase its productivity. Not to mention post-mining land which is almost all very damaged and also covers millions of hectares. And biochar is the right solution that can restore the condition of the land to be fertile again. 

Slow pyrolysis is the best technology for biochar production. But the technology used must be efficient and emissions meet the threshold standards of the country concerned. In addition, excess heat and/or liquid products and gas products from pyrolysis should also be utilized. With the criteria for pyrolysis technology as above, in addition to the quality and quantity of products, namely biochar, can be maximized, the production process also does not cause new problems in the form of environmental pollution. This is very much in line with biochar business activities so that it becomes a solution to the problem of industrial biomass waste from wood and forestry waste as well as a solution to climate problems. Even the utilization of by-products (excess heat and/or liquid products and gas products from pyrolysis) can also encourage the emergence of other environmentally friendly and renewable products.

In economic terms, the outline can be as follows, namely with an investment of 10 million US dollars, approximately 200,000 tons of biochar with more than 400,000 carbon credits will be produced over a period of 10 years. Or if with an investment of 100 million US dollars, almost 2 million tons of biochar and more than 4 million carbon credits will be produced over a period of 10 years. And for example, with a selling price of biochar of 100 dollars per ton and also a carbon credit of 100 dollars per unit (per ton of CO2), then within 10 years the investment has increased 6 times or it only takes about 1.7 years for the initial investment to return (payback period). Of course, when the price of biochar is higher and / or its carbon credits, of course the return on capital will be faster. And that does not include the utilization of liquid and gas products from pyrolysis and excess heat which also have economic potential that is no less interesting. The trend of the future business era will not only focus on financial profit but also provide solutions to environmental problems and climate problems, and of course solutions to social problems by creating jobs.

Biochar to Improve Soil Fertility, Fuel, Industrial Raw Materials or Climate Solutions?

Currently there are still a lot of agricultural wastes (corn stalks, soybean plants, soybean shells and so on) that have not been utilized so that they pollute the environment. Utilizing these wastes so that they become useful products that provide added value is the best solution. What kind of utilization or processing is the best solution for utilizing these wastes? This of course depends on a number of influencing factors such as market readiness, availability and continuity of supply of biomass waste, especially agricultural wastes, technological readiness including technology investment, profits and business continuity, infrastructure and human resources (HR). Production of biochar or charcoal from biomass waste could be the best option. But indeed biochar or charcoal is multifunctional or can be used for a number of uses. Then the question is the use of biochar for what field gives the best results or benefits?

The biochar production is carried out using slow pyrolysis technology. With this technology biochar production can be optimal both in quality and quantity. It is different when using fast pyrolysis technology which produces biooil product or liquid product as the main product, with much less biochar product. Or if you use gasification technology where the main product is gas, so that the proportion of biochar is smaller or it can be considered as a side product, then this will also be less than optimal. These things make choosing the right technology an important thing to be able to give optimal results.

The production of biochar for agriculture has also not become a trend among farmers in Indonesia, so that much of their agricultural waste is not utilized and even pollutes the environment. Another influencing factor is the condition of the agricultural land itself. Dominant and excessive use of chemical fertilizers has damaged agricultural lands so that agricultural productivity continues to decline. And efforts to improve the soil require effort that is not easy and quick so that the fertility of the soil can be restored (recovery) and continues to be maintained for the long term. The combination of using organic materials with certain techniques needs to be done to achieve this. Biochar can also be used to make the use of organic matter more efficient, such as reducing leaching and increasing soil microbial activity. With the increased efficiency of this technique due to the use of biochar, it also minimizes input so that production costs can be further reduced. The integration of agriculture and animal husbandry is a must in order to obtain an adequate supply of organic matter, the quality is maintained and sustainable. Whereas in acid and dry soils, the use of biochar will have a more significant effect.

The use of biochar as an ingredient, especially for bbq and cooking as well as other uses, namely as a reducing agent in steel making. There are not too many uses for BBQ, this is processing or cooking food on a BBQ basis only as a hobby or only for special community segments. And there isn't much biochar for cooking either, or this is more common in Africa, while in Indonesia the option of using firewood or LPG is more common. Likewise, the need for biochar as a reducing agent in steel making is also not much. Meanwhile, the use of biochar for industrial fuels such as boiler fuel and electricity generation is almost non-existent. This is because the production process takes longer (requires a carbonization process), the conversion from biomass to biochar is small (~25%), and the price of biochar is more expensive. Wood pellets and palm kernel shells (PKS) are more of an option for these industrial fuels.

Biochar can also be used as a raw material for various industrial goods for human needs or for the substitution of materials derived from fossils (such as oil and gas) into more environmentally friendly and renewable materials. Materials such as plastic can be replaced with biochar. Particle board, which usually still uses wood waste, can also be replaced with biochar. This trend has not yet occurred, but it is predicted that soon it will become a concern and even a new trend in the industry.

Biochar for climate solutions is likely to become a trend soon. CO2 from the atmosphere is converted into biomass by plants, converted into biochar and stored (sequestration), especially in the soil. The carbon stored in the biochar will not be released into the atmosphere because biochar does not decompose for hundreds or even thousands of years or can be stored permanently. In principle, this is like storing carbon (CO2) with a conservation forest so that it becomes a carbon sink. Trees or plants will absorb CO2 from the atmosphere and be maintained in such a way as to achieve the desired CO2 uptake target then compensated with carbon credits, as well as biochar, how much carbon can be stored (sequestration) then also compensated with these carbon credits. In practice, the use of biochar will be optimal with efforts to enrich the soil on damaged or problematic soils such as post-mining soil, acid soil and diseased soil due to an overdose of chemical fertilizers. Carbon sinks with biochar are easier and cheaper than the carbon capture and storage (CCS) method with CO2 stored beneath in the earth's layers.

To reduce the temperature of the earth by reducing the concentration of greenhouse gases. To reduce 1 ppm of CO2 concentration in the atmosphere is equivalent to absorbing about 15 gigatonnes of CO2. Meanwhile, the costs needed to mitigate major climate change disasters are estimated at USD 1.6 trillion to USD 3.8 trillion each year. To reach the concentration of CO2 in the atmosphere to 350 ppm, around 70,000 biochar the size of the Giza pyramids is needed, assuming that fossil fuels are discontinued. With a volume of the Giza pyramids of 2.6 million m3 and an average biochar density of 200 kg/m3, biochar the size of the Giza pyramids weighs 520 million kg or 520 thousand tons. Huge job of course. Biochar production must grow 5000 times from its current production capacity. With biochar the size of a unit of the pyramids of Giza we need to build 4 pyramids per day (about 2 million tonnes of biochar per day) for the next 100 years and starting now.

Utilization of Excess Energy from Biochar Production with Pyrolysis

Most of the production equipments for biochar are currently obsolete, so that the productivity and quality of the products produced are low, also causing environmental problems, namely air pollution. In equipment with this technology, the production process is also not running efficiently, indicated by the large amount of energy or heat loss so that it is less profitable. Slow pyrolysis technology is the best technology for biochar production because it maximizes the production of a solid fraction (biochar). Meanwhile, other thermal technology group are not so suitable for biochar production, for example fast pyrolysis, the main objective of which is to maximize its liquid product or biooil, gasification is the main objective of maximizing gas or syngas product as well as hydrothermal carbonization (HTC) or wet pyrolysis requiring high pressure operating conditions so that it is difficult to be applied. Modern slow pyrolysis technology will operate autothermal / self sustain fuel, safe, good process control and energy management, so that in this way in addition to energy being used for the pyrolysis process itself, excess energy can also be used for other needs such as electricity or heat production.

There are three main variables for this pyrolysis process, namely heating rate, duration / residence time and temperature. The quality and quantity of biochar are determined by these process variables. For example, biochar production with a temperature of less than 400 C will produce acidic biochar, while biochar production above this temperature will produce alkaline biochar. Currently, the pH of biochar produced ranges from 4 to 12. There are also those who make a category about the pyrolysis temperature for biochar production, namely, low with less than 250 C, medium (250 - 500 C), high with more than 500 C. According to some researches fixed carbon also increased from 56% to 93% at 300 and 800 C pyrolysis temperatures. The surface area also increased from 120 m2 / gram at 400 C to 460 m2 / gram at 900 C. 

And indeed, basically the quality and quantity of biochar is determined by the raw materials used and the conditions of the production process, especially the pyrolysis. In fact, to ensure the quality of biochar, all aspects need to be considered such as raw materials and production processes such as the pyrolysis operating temperature should not be more than 20%, interruptions when production are allowed as long as the conditions of subsequent production parameters are maintained the same as before the restart. The composition of the raw material should not fluctuate more than 15%. And for modern pyrolysis equipment, the excess energy must be utilized with an estimated 35-60% of the energy from the biomass raw material found in pyrolysis gas. A number of agricultural waste processings can use the pyrolysis optimally, including:

1. Palm Oil Industry
The use of pyrolysis technology for palm oil companies, especially in Indonesia, is currently ideal. This is because palm oil mills or CPO mills produce a lot of solid waste biomass namely, empty fruit bunches/EFB, fiber and palm kernel shell. And because palm kernel shell / PKS has a lot of demand both from within and outside the country for industrial fuel and power plants, this PKS should not be used as raw material for pyrolysis or biochar production, but can be directly used as a trading commodity.  The EFB and fiber are used as raw material for biochar and then the biochar is used to improve the soil quality of palm oil plantation so that fresh fruit bunch or FFB productivity increases. Excess energy from pyrolysis is then used as boiler fuel so that it can reduce or even replace all PKS as the the boiler fuel. And because the boiler fuel is replaced with the excess energy pyrolysis, so can be  all of the PKS can be sold. 

2. Integrated Coconut Industry

Products from coconut processing such as copra, dessicated coconut, and nata de coco require heat in the production process. Coconut shell charcoal is also a favorite charcoal with a large market demand. The charcoal will usually be further processed into briquettes for energy and activated carbon for various industries. For biochar production, coconut industrial wastes such as coir/fiber, bunch and midrib can be used. Excess energy of pyrolysis can be used for the production of the above products and other advanced products. The low productivity of Indonesian coconut production needs to be improved, one of which is by improving soil quality with biochar. In addition, there are so many coconut plantations in Indonesia that need to be replanted so that improving soil quality to achieve the desired production is increasingly important. 

3. Corn Plantation

Efforts to increase food products need to be taken seriously, this can be done in two ways, first by expanding the land or making new rice paddy fields for production and the second by improving the quality of existing land so that productivity will increase. Biochar is very effective and efficient for the second method above. Besides being used as a human food source, corn is also used for animal feed. With the projection of the human population continuing to increase, the need for food either directly by consuming corn or indirectly from livestock such as meat and eggs. Poultry or chicken feed production ranks first of other animal feed production, or in the world almost half of the animal feed produced is chicken feed. Corn cobs and husks are agricultural waste that can be used for biochar production. Excess energy from the pyrolysis process can be used for drying corn and other advanced processes.

4. Rice Paddy Farming 

Rice or paddy is the staple food of most of the Indonesian population. The area of irrigated rice fields is decreasing throughout the year. This encourages the use of non-irrigated rice fields or dry land for the production of this rice. Biochar is able to improve the quality of dry land soils, such as in corn farming. Rice husks are rice paddy agricultural waste that can be used for biochar production. Excess energy from rice husk pyrolysis can be used for drying the rice paddy itself so that it becomes dry grain ready to be milled, or for other purposes. With the improvement of soil quality, rice productivity can be increased and it is not impossible that food self-sufficiency, especially rice, can be achieved, as has been achieved by Indonesia some time ago.

Which is Better, Efficient Boiler or Pyrolysis System ?

Fiber and palm kernel shells (PKS) are palm oil mill solid wastes that are produced in CPO production in that mill. The amount of fiber and PKS waste is quite a lot, which is around 20% of each fresh fruit bunch (FFB) or almost the same as the CPO produced. A palm oil mill with a capacity of 60 tons / hour FFB can produce fiber as much as 8.1 tons per hour or 194.4 tons per day and PKS of 3.3 tons / hour per hour or 79.2 tons per day. And because both of them are waste, generally the utilization of the waste is not initially considered, including for use as fuel in boilers in palm oil mills for the production of electricity and steam. The use of fiber and PKS for boiler fuel generally uses 100% fiber and about 30% of the PKS. Under these conditions the remaining 70% of the PKS can be used for other things including being sold or even exported.

When the shell becomes a commercial commodity and demand is greater, palm oil mills replace their old inefficient boilers with new boilers that have a high level of efficiency. In this way, 100% of the PKS is no longer used to boiler fuel and only requires fiber as fuel. In this condition a paradigm shift in thinking begins to occur, that is when the solid waste is almost unnoticed and tends to be considered a problem, then it becomes an important part of earning additional income and it can even be estimated that if the shell is successfully sold then it is sufficient to cover the operational costs of the palm oil mill. Certainly something interesting if the production of CPO (crude palm oil) with 0% operational costs so that profit is increasingly attractive especially amid the recent decline in CPO prices.

Another thing that can be done is to use a pyrolysis unit, to run the boiler. With pyrolysis, not only fiber is used but also the empty fruit bunch (EFB). EFB are solid palm oil mill waste which to date have generally not been utilized. Besides producing energy, pyrolysis also produces products in the form of charcoal (biochar). Although charcoal (biochar) can also be used for energy sources, but in the business of palm oil companies the use of biochar for plantations can be more compatible. The use of biochar in palm oil plantations is mainly to  fertilizer saving, which is one of the major cost components (around 30%) in the CPO production business. With an area of ​​20 thousand hectares of oil palm plantations, fertilizer costs are estimated to reach Rp. 71.50 billion (around US$ 5 million) per year or Rp. 35.75 billion (around US$ 2.5 million) per year for every 10,000 hectares, for more details, please read here. Palm oil mills with big vision certainly try to maximize their potential with the aim of maximizing profits from upstream to downstream production activities. With Biochar can also target the increase in productivity of FFB, for more details, please read here.

The application of biochar will be easier to do in Indonesia than in Malaysia, this is because almost all palm oil mills in Indonesia also have palm oil plantations while in Malaysia the mills generally do not have their own palm oil plantations. The palm oil industry also has an important role for the two countries because Indonesia and Malaysia are the largest CPO producers and owners of biggest palm oil plantations in the world today. The palm oil industry contributes around 7% of Malaysian GDP and 3% of Indonesian GDP, so its role cannot be ignored. Both with pyrolysis and high efficient boilers, biomass waste can be used as an energy source and 100% of the PKS can be commercialized, but with pyrolysis is better because waste of EFB can also be processed, there are biochar product (while only ash if only with regular combustion) for Fertilizers saving in the palm oil plantations and the exhaust gases from the palm oil mill boilers are also clean because they burn gas (syngas) produced from the pyrolysis process. 

Owls, Cobra Snakes or Liquid Smoke to Repel Mice at Palm Oil Plantations?

Mice are animals that disrupt various human activities so they must be expelled or killed. Many stories from farmers who experienced crop failure due to rampant rat pests. Likewise in palm oil plantations, rats will damage the palm fruit. Biological countermeasures are mostly carried out, namely with owls and cobra snakes. While other efforts that can be done is by liquid smoke. Aside from being used for fertilizer, liquid smoke can also be used to repel these mice. A strong aroma and an acidic nature will make the mice away from the palm oil trees that have been given liquid smoke. The longer the effect of liquid smoke on the palm oil tree the longer the mice away from the palm tree.

Liquid smoke does not harm humans and can be produced in large quantities. Besides that liquid smoke also comes from biomass (pyrolysis) so that it is an environmentally friendly chemical and from renewable sources. Empty bunches or EFB which have generally not been utilized by palm oil mills can be used for the production of liquid smoke. In addition to liquid smoke, biochar is also produced which is also very useful in the palm oil plantations, for more details, please read here. Production of liquid smoke and biochar from EFB will also be a solution to handling solid waste in the form of empty bunches. The production of biochar and liquid smoke for large scale can be done only with continuous pyrolysis units, for more details, please read here.

While when biochar and liquid smoke are used in oil palm plantations, the pyrolysis product in the form of syngas and biooil can be used for boiler fuel. When syngas and biooil are used as fuel, palm kernel shells and a number of mesocarp fibers can be sold or exported like CPO. PKS (palm kernel shell) or shell can be exported directly to Japan or Korea. Whereas mesocarp fiber can be made pellets or briquettes before being exported. Production of pellets or briquettes from mesocarp fiber is almost the same as the production of wood pellets or sawdust briquettes, for reference can be read here and here.

Back to the laptop. So the production of liquid smoke from pyrolysis of empty palm bunches is more likely to be a solution to overcome rat pests in addition to various other advantages for palm oil plantations and mills. In addition, liquid smoke can also be used for fertilizers and is not harmful. Even to optimize the control of rodent pests is very possible with a combination of liquid smoke with owls and cobra snakes.

EFB Biochar and Fertilizer Savings in Palm Oil Plantations

High palm oil plantation productivity and high oil yield has always been a goal in the palm oil business. The nutrient estimates needed to produce 25 tons of FFB / ha / year were 192 N, 11 P, 209 K, 36 Mg, and 71 Ca in kg / ha / year. With the production of 25 tons of FFB / ha / year palm oil or CPO crude will produce around 6.5 tons (25% of FFB). Analogy in the field of animal husbandry where the feed component holds 75% of production costs or is the highest cost component, as well as fertilizer, especially in palm oil plantations. Fertilizer is the most expensive cost or 60% of total maintenance costs. To achieve this productivity, the calculation practically of the need is more or less as follows: an afdeling with an area of ​​1,000 hectares with 1 hectare consisting of 143 trees, so there are 143,000 trees of palm oil. If the dose per tree is 2.5 kg, then the fertilizer needs are 357,500 kg (357.5 tons), with the price of non-subsidized chemical fertilizers for example Rp 10,000 / kg, the cost incurred is 3,575,000,000 (Rp. 3,575 billion or US$ 238,333). If an area of ​​10,000 hectares means fertilizer needs of Rp. 35.75 billion (US$ 2,383,33), whereas if the oil palm plantation is 20,000 hectares, it will reach Rp. 71.50 billion (US$ 4,766,667). Of course an amount that is not small.

The question is what efforts can be made to reduce fertilizer costs but increase palm productivity. One contradictory thing seems to be because it reduces the supply of fertilizer but expects high productivity. This is where we need to examine and explore the facts that occur in the field. With a tropical climate and high rainfall, it makes large leached fertilizers. A condition, for example in hilly and bumpy areas, when the rain falls, the fertilizer that is washed is very large, even in vain fertilization is done because it is not absorbed by the palm trees as the target. The high level of leaching from the use of fertilizers by rainwater makes only available a small amount of available fertilizer in real terms or a number of analyzes said averaging only 50%. With the available fertilizers there are only a few that are also automatically absorbed by the palm trees. When for example washing (leaching) can be reduced by only 30%, it means that the fertilizer that is still available becomes 70%, so that the fertilizer is absorbed more and more and the productivity of the palm oil fruit also increases.

The initial stage that can be done is the cost of the same fertilizer but the productivity of the palm oil fruit can increase up to for example 30%. Furthermore, if this can be achieved, fertilizer consumption will be reduced for example up to 30% but palm oil productivity can be maintained at that level. This is possible when biochar has become a microbial colony and the quality of the soil increases so that uptake of fertilizer is maximal. Biochar is one of the media that can be used for this. An empty fruit bunch that is widely available in palm oil mills and is generally not utilized as a raw material for biochar production. A palm oil mill with a production capacity of 60 tons / hour FFB will produce EFB 13.2 tons / hour so that if the palm oil mill operates 20 hours / day the EFB produced 264 tons / day. The production of biochar with pyrolysis can also produce liquid smoke which can also be used as fertilizer.

Why can biochar be used to increase palm oil productivity and even reduce fertilizer consumption? This is because biochar with its pores with a surface area of ​​about 200 m2 / gram can hold the fertilizer from washing, maintain moisture and many soil microbes that can live in these pores thus improving the physical and chemical properties of the soil. Biochar can last up to hundreds of years in the soil so it does not need to be added every year when the amount is sufficient. Biochar implementation can be started from small scale to massive scale. To process empty fruit bunches (EFB)  in the palm oil mill into biochar, a continuous pyrolysis equiment is needed, to be more clearly read here. To monitor the effectiveness of biochar on oil palm plantations today can use internet technology or IoT (Internet of Things) and for more details can be read here and here.

Production of Biophenol, Bioformaldehyde and Wood Adhesive from Pyrolysis Liquid Products

The byproducts of biomass (slow) pyrolysis are liquid and gas products. The liquid products consist of biooil and biomass vinegar (pyroligneous acid). Biooils can be directly used as fuel with a particular burner, or can also be upgraded to the vehicle fuel. Meanwhile, if used for non-energy products, can be used for the production of green chemical or renewable chemicals such as BioFormaldehyde and wood adhesive. While the aqueous phase of pyrolysis liquid product that is biomass vinegar (pyroligneous acid) can be used for feedstock biophenol production. Previously biomass vinegar has been known for various uses such as latex coagulant, anti-termite and fertilizer. While the biophenol production process scheme of biomass vinegar as follows.

Global consumption for phenol currently reaches 20 million tons or worth 20 billion US dollars (280 trillion rupiah). Renewable phenol or biophenol can substitute phenol which has been produced based on petroleum. Excess heat and excess syngas from the pyrolysis process can be used for the production process of the biophenol as energy sources. An integrated and efficient production unit will produce highly competitive products, such as the pyrolysis process which is primarily charcoal, and from its by-products made derivative products that are desperately needed today.

Activated Carbon For Any Industries!

Activated carbon or activated charcoal is a material that is widely used in various industries, as auxiliary processing. Food, beverage, energy, mining and pharmaceutical industries use this activated carbon. The need for activated carbon also continues to increase so that production also needs to be expanded. Indonesia has great potential as a world class activated carbon producer considering the abundance of potential raw materials available.

Currently, large activated carbon producers are located outside Indonesia such as Europe and America. Yet neither Europe nor America have abundant source of raw materials or most imports including from Indonesia. The most favorite activated carbon feedstock today is coconut shell and once again Indonesia is the country with the largest coconut plantation in the world, which is about 3.7 million hectares. Palm kernel shells can also be the raw material of further choices. With a palm oil plantation area of approximately 12 million hectares, palm kernel shells produced more than 10 million tons / year.

The raw material of activated carbon is charcoal. The charcoal is then activated to become activated carbon. The process of making charcoal is by carbonization or pyrolysis. Coconut shell as an example of raw material of charcoal, then after carbonization the coconut shell convert into coconut shell charcoal, which then this charcoal become the raw material of activated charcoal. So basically the process of activated charcoal production is through 2 stages of the process namely pyrolysis (carbonization) and activation. The process of producing the charcoal or the carbonization process (pyrolysis) is the same as the biomass carbonization process in general, for more detail can be read here. Currently in large capacity the production of charcoal is carried out continuously with indirect-heating. Rotating kilns and heated auger pyrolyser are commonly used equipment for continuous production of charcoal. Continuous integration of charcoal production and activation process can be read here.

While the activation phase can be done in two ways namely the activation of physics and chemistry. The choice of activation depends on the target surface area, pore distribution and economy. Steam activation is the most widely used physics activation, whereas chemical activation is very diverse. The more surface area of activated carbon the more expensive the price is also proportional to the cost of production. Activation equipment commonly used there are 2 kinds namely, rotating kilns and fluidized bed. Of these 2 types of rotating kiln equipment is more widely used than the fluidized bed. The price of rotating kiln equipment is cheaper because the construction and operation are easier than the fluidized bed system. Fluidized bed systems are typically used for higher quality activated carbon production due to better distribution and pore engineering due to fluidization.

Standard and quality of activated carbon is determined primarily by surface area, pore distribution, size and hardness. The iodine number parameter is commonly used for the quality of activated carbon. The higher the iodine number the better the activated carbon quality. The iodine number is a number indicating how much adsorbent or activated carbon can adsorb iod. The greater the iodine value, the greater the adsorption power of the adsorbent or the activated charcoal. Conversely, the higher water content and ash content contained in the activated carbon will cause many pores to be covered by the impurities so that the surface area will be smaller. Where the surface area is closely related to the activated carbon adsorption capacity.All biomass basically can be used as an activated carbon raw material because it has a carbon content. Specific application of the activated charbon that determines the choice of raw material and its activation options.

Compaction Will Increase The Biomass Heating Value?

Many people think that with biomass like sawdust when compacted it will increase the heat or the heating value, but that is not entirely correct. Densification into pellets or briquettes does raise to solid or density so that the weight or mass is high while the volume is small, for example sawdust when not compacted its density is only about 200 kg / m3 and after solidified (densificated/compacted) into pellet to 650-700 kg / m3 and can be more than 1,000 kg / m3 when briquetted. This makes the biomass efficient for long-distance transport, easier handling, burning and so on.

Indeed before compacted into pellets or briquettes, the solid biomass must have a 5-10% dryness rate that can be compacted. When the biomass is wet or has a high water (moisture) content, then drying it will increase the calorific value. While the biomass initially very dry say with a moisture content of less than 5% then to reach the desired level of dryness (5-10%) then the need for additional water or wetted of course this does not increase the calorific value but instead reduce the calorific value. So the increase in calorific value of biomass can be done by reducing its water content or drying it even down to minimize its volatile matter and increase its carbon content (fix carbon). The pyrolysis process of both torrefaction (mild pyrolysis) and carbonization  (slow pyrolysis) is the process of increasing the heating value of the solid biomass.

 

Example of pellet fuel types. A photo taken from here

Well after the increased calorific value through drying up to pyrolysis then followed by the compaction process will be the better quality of fuel is in terms of heating value and volume. For example, when wood charcoal has an 85% fixed carbon with a calorific value of 7500 kcal/kg with a density of 400 kg/m3 and then made into pellet with a density of 650 kg / m3 then in volume 1 m3 has a higher heat content of 3,000,000 kcal in wood charcoal and 4.875.000 kcal on pellet or because its density is higher.

Activated Carbon Production From Coconut Shell and Palm Kernel Shell

Magnification of the surface area due to the increasing number of micro pores that have great adsoroption ability is the main purpose of the production of activated carbon. Characteristics of the pores and even then vary depending on the application or use of activated carbon as an example the pores of the activated carbon used in the liquid, will be different which is used in gas substances. Characteristics of the pores can be designed and made during the production process. Basically the manufacture of activated carbon will involve high temperatures and adjuvant activating that can be a steam, CO2 or chemical, depending on the characteristics of activated carbon, or more specifically in the pores of activated carbon are generally calculated  by its surface area of the activated carbon. Additionally hardness of activated carbon is also other important quality factors of the activated carbon. This article is a continuation of my previous article about the production of charcoal from coconut shell and palm kernel shell continuously. Alhamdulillah can be done writing.

Activated charcoal production requires charcoal as raw material. The charcoal can be produced in both traditional and modern process. Charcoal quality will affect the quality of the final product of activated carboon. Modern charcoal production continuously be able to make the whole process of the activated carbon production becomes efficient when both are integrated into one. In the process of making charcoal which usually need to be cooled beforehand so into charcoal, then it can not be done when the production of charcoal continuously. Results of carbonization directly into the activation unit with only slightly raise its temperature, ie, if the carbonization ranging from 600 C and the activation of about 900 C. When using raw charcoal from the traditional process as a raw material, it takes far more energy to achieve the activation temperature of about 900 C.

Once out of the activation process, the active carbon is cooled by removing a number of considerable heat. Heat is released in large enough quantities can be used for drying coconut shell or palm kernel shell, giving it a special process of carbonization become more efficient as well as a whole with the activation. Activation adjuvant to be inserted in the activation process is well regulated its operating conditions of temperature, pressure and residence time to get the quality and quantity of activated carbon desired. In the activation condition, likened charcoal is material be punched by the activation of materials at high heat. There are many variants of activated carbon can be designed specifically for their intended use, so that the operating conditions and auxiliaries activation there are also variations.

The use of activated carbon, especially in the food industry (food) including beverages and pharmaceuticals, precious metals refinery (favor) and the oil and gas industry. Once the extent and magnitude of this use of activated charcoal so it is a great opportunity also for Indonesia, which has the best raw materials are also the largest quantity in the world of coconut shell and palm kernel shell. Will this also would be ignored? It should not. InsyaAllah