
Exhaust gas emissions, especially from coal
power plants, must be made environmentally friendly. About 60% of the world's
electricity currently depends on coal, this is because coal power plants can
provide electricity at low prices. The exhaust gases that pollute and endanger
the environment need to be treated in such a way that they no longer endanger
the environment. Coal is a fuel that contains a high enough sulfur content,
namely 0.5% (5 kg / ton of coal) so that when it is burned, it will cause SO2
and SO3 gas emissions or the SOx gas group. If these gases are emitted in the
atmosphere, they will cause acid rain. The acid rain will damage agricultural
land, forests due to imperfect photosynthesis, the death of marine life and
corrosion of metal objects such as vehicles, buildings and so on, even human
health in the form of respiratory problems such as asthma, chronic bronchitis
to permanent lung damage.
For example, China says more than half of the
country's cities experience acid rain and only a few have fresh air. One sixth
of the major rivers are so polluted that their water is deemed unsuitable for
agriculture. Pollution watchdogs say 16.4% of China's major rivers do not even
meet agricultural irrigation standards. Water from big cities such as Shanghai,
Tianjin and Guangzhou is said to be highly polluted. Only the tourist island
area of Hainan and parts of the northern coast are considered truly healthy.
Only 3.6% of the 471 cities monitored received the top ranking in terms of air
cleanliness.


Efforts to minimize SOx gas emissions
(including sulfur dioxide (SO2), sulfur monoxide (SO), and sulfur trioxide
(SO3)) are carried out by treating flue gas desulphurisation or
the term FGD (Flue Gas Desulphurisation). As of June 1973, there were 42 FGD
units operating, 36 in Japan and 6 in the United States, with capacities
ranging from 5 MW to 250 MW. Between 1999 and 2000, FGD units were in use in 27
countries, and there were 678 FGD units operating at a total power generation
capacity of about 229 gigawatts. About 45% of the FGD capacity is in the US,
24% in Germany, 11% in Japan, and 20% in various other countries. Approximately
79% of the units, representing about 199 gigawatts of capacity, use wet
limestone. About 18% (or 25 gigawatts) use spray-dry scrubbers or sorbent
injection systems. The use of these FGDs has now been introduced to various
places that use fossil fuels such as coal incinerators and waste incinerators.
Basically there are several types of FGD
techniques but in general they can be divided into 2, namely the wet method,
for example by absorption of wet lime or sea water solutions, dry methods such
as activated carbon and semi-dry methods. The wet method is the method most
widely used. The "gypsum lime method", which is one of the wet
methods, has become a mainstream in the world as a large capacity exhaust gas
treatment process especially for thermal power plants. The considerations for
selecting the FGD technique include scale, cost, types of by-products, and
their application. The lime-gypsum method complicates the gypsum recovery
process and the wastewater treatment process, so it is not suitable for
application in small boilers. Therefore, in small-scale plants, the "magnesium hydroxide method" which uses magnesium
hydroxide, which is a cheap alkaline in addition to lime, is often used. The
soda method was a wet method commonly used in pulp mills and small-scale
equipment in the second half of the 1960s, but because caustic soda as an
absorber is expensive and operating costs are high, a method using magnesium
hydroxide, which is a cheaper absorber, has been adopted.

In the 1960s, Japan developed a lot of dry FGD
techniques and since the 1980s wet FGD techniques have been widely used until
now. Currently, Japan has all installed the FGD equipment, but it is certain
that the need in China and Southeast Asia will increase in the future.
Therefore, in recent years, most FGD equipment manufacturers have realized the
technological developments being applied to overseas markets, and the
development of simple desulphurisation devices suitable for developing
countries that are easy to operate and low cost is underway. There is also a
by-product from the FGD which has economic value, namely the gypsum FGD. In
Indonesia, there is only one coal power plant that uses FGD with wet
limestone and produces a gypsum FGD, namely at PLTU Tanjung Jati, Jepara,
Central Java. Meanwhile, other coal power plants still use wet technique
with sea water absorbtion.
The desulphurisation method with activated carbon is also simultaneous with denitration and functions to remove other
components such as removing dioxins and removing heavy metal elements. The
activated carbon adsorption method consists of an adsorption tower, a
desorption tower, and an activated carbon circulation transfer device. When
other components such as NOx are also adsorbed, a module consisting of a number
of activated carbon cells forms an adsorption tower, and each component in the
exhaust gas is removed as it passes through each module.

Activated carbon which has adsorbed SOx, etc. In the adsorption tower it is sent to the desorption tower, heated to 350 ° C or higher, and regenerated. The regenerated activated carbon is cooled to 150 ° C or lower in the cooling section, then the dust is removed by filtration and reused in the adsorption tower. Instead, the concentrated SO2 gas obtained is washed and purified, then oxidized or reduced, and finally recovered as sulfuric acid, elemental sulfur, or the like.
Activated carbon has a large surface area
because of the many pores on its surface. These pores are intentionally made to
increase the efficiency of adsorption. The more pores are formed, the wider the
activated carbon surface area. Based on the size of the pores, they are divided
into macropore, mesopore and micropore. Activated carbon from coconut shells
has many micropores, while activated carbon from wood is dominated by mesopore
and macropore (micropore only has a small portion) because the wood structure
is also more open. For activated carbon from coal, the distribution of
micropore, mesopore and macropore is almost evenly distributed. Based on the
above characteristics, coconut shell activated carbon is widely used to absorb
small molecules from gas and liquid. Activated carbon from coconut shells and
palm
kernel shells (PKS) is thought to be the
most suitable for the FGD (flue gas desulphurisation) process.